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KMID : 1035320220490040199
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Korean Society for Dental Materials
2022 Volume.49 No. 4 p.199 ~ p.212
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A study on coating of collagen-containing hydroxyapatite on titanium using electrochemical deposition method
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Choi Byung-Han
Park Yeong-Joon
Song Ho-Jun
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Abstract
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In this study, a biomimetic coating in which hydroxyapatite (HAp) and collagen (Col), the major components of bone, were coated together on titanium was performed using the ECD method. The polished CP-Ti (commocially pure?titanium) disks (Ti-As), and the roughened CP-Ti disks (Ti-R) fabricated by anodic oxidation method were prepared. An electrolyte (E) was prepared by mixing Ca(NO3)2 and NH4H2PO4. Collagen-contaiing electrolyte (ECol) was prepared by adding collagen (Type-I) to E electrolyte. A pulse-type negative electric current of -5 mA, -10 mA, and -15 mA was applied to the titanium specimens, respectively. The temperature of electrolyte solution was maintained at 37℃. The fabricated specimens were named to Ti-As-E-5, Ti-As-E-10, Ti-As-E-15, Ti-As-ECol-5, Ti-As-ECol-10, Ti-As-ECol-15, Ti-R-E-5, Ti-R-E-10, Ti-R-E-15, Ti-R-ECol-5, Ti-R-ECol-10, and Ti-R-ECol-15, respectively. The nanorod-shaped crystallites were evenly formed on the surface of Ti-As-E groups. The length of nanorods on Ti-As-ECol groups was shorter than that on Ti-As-E groups. A low crystalline HAp structure was detected in X-ray diffraction (XRD) patterns of Ti-As-E groups. For Ti-As-ECol groups, the HAp structure was confirmed by analysis of the selected area electron diffraction (SAED) patterns obtained from a transmission electron microscope (TEM). Fourier-transform infrared spectroscopy (FT-IR) spectra of Ti-As-ECol groups showed the amide peaks assigned to collagen and related to carbonate apatite. Similarly to the Ti-As specimens, HAp crystallites were coated on Ti-R-E and Ti-R-ECol groups and their surface roughness was maintained. It is expected that the results of this study could be applied to the development of a biomimetic surface treatment method for titanium implants.
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KEYWORD
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Titanium, Surface modification, Electrochemical deposition, Hydroxyapatite, Collagen
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